Temperature-dependent self-assembly of a purely organic cage in water.
نویسندگان
چکیده
Using a novel dynamic covalent approach relying on reversible hydrazone formation, a purely organic 3-dimensional prismatic cage was developed in water at elevated temperatures. By lowering the temperature, the hydrazone bond becomes kinetically inert. This self-assembled cage acts as an effective receptor for donor-acceptor pairs, whose interactions are weak in the absence of the cage.
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ورودعنوان ژورنال:
- Chemical communications
دوره 54 25 شماره
صفحات -
تاریخ انتشار 2018